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Adipogen/Ohira-Bestmann Reagent/CDX-D0501-G001/1 g

MoreInformation
ProductDetails
SynonymsDimethyl(1-diazo-2-oxopropyl)phosphonate;Ohira-Bestmannphosphonate;α-Azido-α-(dimethylphosphono)acetone
ProductTypeChemical
Properties
FormulaC5H9N2O4P
MW192.11
CAS90965-06-3
Source/HostChemicalsSynthetic.
PurityChemicals≥96%(HPLC)
AppearanceYellowliquid.
SolubilitySolubleinacetonitrile.
IdentityDeterminedby1H-NMR.
DeclarationManufacturedbyChemodex.
OtherProductDataClickhereforOriginalManufacturerProductDatasheet
Ourproductdescriptionmaydifferslightlyfromtheoriginalmanufacturersproductdatasheet.
InChiKeySQHSJJGGWYIFCD-UHFFFAOYSA-N
ShippingandHandling
ShippingAMBIENT
ShortTermStorage+4°C
LongTermStorage-20°C
HandlingAdviceProtectfromlightandmoisture.
Use/StABIlityStableforatleast2yearsafterreceiptwhenstoredat-20°C.
Documents
MSDSNo
ProductSpecificationSheet
DatasheetDownloadPDF
UsedintheSeyferth-Gilberthomologationwhichisachemicalreactionofanarylketoneoraldehydewithdimethyl-ordiazomethyl-phosphonateandpotassiumtert-butoxidetogivesubstitutedalkynes.
ProductReferences
(1)P.Callantetal.;SyntheticCommunications14(2),155-61(1984)|(2)S.Ohira;SyntheticCommunications19(3-4),561-4(1989)|(3)S.Kasterenetal.;Nature446(7139),1105-1109(2007)|(4)G.J.Rothetal.;Synthesis(1),59-62(2004)
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