产品资料

alfa/A11014Bis(pentafluorophenyl)phenylphosphine, 97%/0.25g/A11014.01

Bis(pentafluorophenyl)phenylphosphine, 97%

MDL

MFCD00000291

EINECS

225-780-1

化学性质

化学式

C₁₈H₅F₁₀P

式量

442.20

熔点

59-64°

沸点

105°/0.3mm

闪点

>110°(230°F)

Storage & Sensitivity

Ambient temperatures.

可溶性

Soluble in chloroform, dichloromethane, tetrahydrofuran, benzene, toluene, ethanol, methanol, and supercritical carbon dioxide.

应用

Bis(pentafluorophenyl)phenylphosphine is used as a ligand involved in the palladium-catalyzed Heck reaction of iodobenzene and styrene in compressed carbon dioxide. It is also used in the polymerization of 1,3-butadiene with Co(2-ethyl hexanoate)₂.

注释

Store in a cool place. Incompatible with strong oxidizing agents, strong reducing agents, strong acids and bases.

参考文献

Gallotta, F. D. C.; Christensen, J. H. Source identification of petroleum hydrocarbons in soil and sediments from Iguaçu River Watershed, Paraná, Brazil using the CHEMSIC method (CHEMometric analysis of Selected Ion Chromatograms). J. Chromatogr. A 2012, 1235,149-158.

Kristensen, M.; Johnsen, A. R.; Christensen, J. H. Marine biodegradation of crude oil in temperate and Arctic water samples. J. Hazard. Mater. 2015, 300, 75-83.

GHS危险和防护声明

危险说明（欧盟）:H302+H312+H332-H315-H319-H335

Harmful if swallowed. Harmful in contact with skin. Harmful if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

防范说明:P261-P264b-P270-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P330-P362-P403+P233-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Take off contaminated clothing and wash before reuse. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/ container to an approved waste disposal plant

其他参考资料

拜耳斯坦登记号

6253897

协调关税代码

2931.39

有毒物质控制法

文件

产品 SDS

质量分析报告(COA)

产品说明书

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