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Ossila/UGH-2 | 40491-34-7/1 g/M2131A1

1,4-Bis(triphenylsilyl)benzene, known as UGH-2, is one of the well-known TADF host materials for blue-emitting dopants (such as FirPic) in highly-efficient blue PhOLEDs. This is due to its wide energy gap (4.4 eV) and high triplet energy (ET = 3.5 eV).

With a very deep HOMO energy level (HOMO = 7.2 eV), UGH-2 also works as an electron-transport (ETL) and hole-blocking layer (HBL) material.

General Information

CAS number40491-34-7; 18856-08-1
Full name1,4-Bis(triphenylsilyl)benzene
Chemical formulaC42H34Si2
Molecular weight594.89 g/mol
Absorptionλmax 265 nm in DCM
Fluoresceneλem 298 nm in DCM
HOMO/LUMOHOMO = 7.2 eV, LUMO = 2.8 eV (ET = 3.5 eV)
SynonymsUGH2, 1,4-Phenylenebis(triphenylsilane)
Classification / FamilyOrganic electronics, Hole-blocking layer materials (HBL), TADF blue host materials, Blue PhOLEDs, TADF-OLEDs, Sublimed materials.

Product Details

PuritySublimed: >99.0% (HPLC)
Melting pointTGA: >270 °C (0.5% weight loss)
ColourWhite powder/crystals

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

Chemical Structure

UGH-2 chemical structure
Chemical structure of UGH-2

Device Structure(s)

Device structureITO/MoOx (5 nm)/NPB (40 nm)/TCTA (5 nm)/3% Y-Pt :mCP(20 nm)/8% FIrpic:UGH2 (20 nm)/TAZ (40 nm)/LiF (0.5 nm)/Al (100 nm) [1]
ColourWhite white
Max. Current Efficiency29.8 cd/A 
Max. EQE10.3%
Max. Power Efficiency19.7 lm W-1
Device structureITO/MoOx (5 nm)/NPB (40 nm)/mCP(10 nm)/2% Y-Pt:8% FIrpic:UGH2 (20 nm)/TAZ (40 nm)/LiF (0.5 nm)/Al (100 nm) [1]
ColourWhite white
Max. Current Efficiency28.5 cd/A 
Max. EQE9.1%
Max. Power Efficiency21.3 lm W-1
Device structureITO/MoO x (5 nm)/NPB (40 nm)/4% Y-Pt :TCTA (20 nm)/8%FIrpic:mCP(10 nm)/8% FIrpic:UGH2 (10 nm)/BAlq (40 nm)/LiF (0.5 nm)/Al (100 nm) [1]
ColourWhite white
Max. Current Efficiency45.6 cd/A 
Max. EQE16.0%
Max. Power Efficiency35.8 lm W-1
Device structureITO/TAPC (30 nm)/TCTA (10 nm)/CzSi (3 nm)/CzSi doped with 4 wt% of 2c* (25 nm)/UGH2 doped with 4 wt% of 2c*(3 nm)/UGH2 (2 nm)/TmPyPB (50 nm)/LiF (0.8 nm)/Al (150 nm) [2]
ColourBlue blue
Max. Current Efficiency22.3 cd/A
Max. EQE11%
Max. Power Efficiency16.7 Im/W
Device structure(ITO)/a-NPD (30 nm)/TCTA (20 nm)/CzSi (3 nm)/CzSi doped with 6 wt% [Ir(fppz)2(dfbdp)] (35 nm)/UGH2 doped with 6 wt% [Ir(fppz)2(dfbdp)] (3 nm)/UGH2 (2 nm)/BCP (50 nm)/Cs2CO3 (2 nm)/Ag (150 nm) [3]
ColourBlue blue
Max. Current Efficiency11.4 cd/A
Max. EQE11.9%
Max. Power Efficiency7.9 Im/W
Device structureITO/2-TNATA (30 nm)/TAPC (30 nm)/TCTA (10 nm)/mCP:8 wt.% (F2CF3Ch2ppy)2Ir(pic-N-oxide)* (20 nm)/UGH2:15 wt.% (F2CF3Ch2ppy)2Ir(pic-N-oxide) (10 nm)/BAlq (40 nm)/LiF (1 nm)/Al (100 nm) [4]
ColourBlue blue
Max. Current Efficiency36.1 cd/A
Max. EQE23.3%
Max. Power Efficiency17.3 Im/W
Device structureITO/TAPC (40 nm)/mCP (10 nm)/UGH2:10 wt.% FIrpic (20 nm)/ 3TPYMB (40 nm)/LiF (1 nm)/Al (100 nm) [5]
ColourBlue blue
Max. Current Efficiency49 cd/A
Max. EQE23%
Max. Power Efficiency31.6 Im/W

*For chemical structure information, please refer to the cited references.

Pricing

 GradeOrder CodeQuantityPrice
Sublimed (>99.0% purity)M2131A1100 mg£189.00
Sublimed (>99.0% purity)M2131A1250 mg£379.00
Sublimed (>99.0% purity)M2131A1500 mg£636.00
Sublimed (>99.0% purity)M2131A11 g£1020.00

MSDS Documentation

UGH-2 MSDSUGH-2 MSDS sheet

Literature and Reviews

  1. High Efficiency White Organic Light-Emitting Devices Incorporating Yellow Phosphorescent Platinum(II) Complex and Composite Blue Host, S-L. Lai et al., Adv. Funct. Mater. 2013, 23, 5168–5176 (2013); DOI: 10.1002/adfm.201300281.
  2. Iridium(III) Complexes of a Dicyclometalated Phosphite Tripod Ligand: Strategy to Achieve Blue Phosphorescence Without Fluorine Substituents and Fabrication of OLEDs, C-H. Lin et al., Angew. Chem., 123, 3240 –3244 (2011); DOI: 10.1002/ange.201005624 .
  3. En Route to High External Quantum Efficiency (~12%), Organic True-Blue-Light-Emitting Diodes Employing Novel Design of Iridium (III) Phosphors, Y-C. Chiu et al., Adv. Mater., 21, 2221–2225 (2009); DOI: 10.1002/adma.200802546.
  4. Deep-blue phosphorescent iridium complexes with picolinic acid N-oxideas the ancillary ligand for high efficiency organic light-emitting diodes, H-J. Seo et al., Org. Electron., 11, 564–572 (2010); doi: 10.1016/j.orgel.2009.12.014.
  5. High efficiency blue phosphorescent organic light-emitting device, N. Chopra et al., Appl. Phys. Lett. 93, 143307 (2008); doi: 10.1063/1.3000382.

To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.

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