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Ossila/Ir(btpy)3 | Tris(2-(benzothiophen-2-yl)pyridineiridium | 405289-74-9/500 mg/M491188bio精品生物—专注于实验室精品爆款的电商平台 - 蚂蚁淘旗下精选188款生物医学科研用品
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Ossila/Ir(btpy)3 | Tris(2-(benzothiophen-2-yl)pyridineiridium | 405289-74-9/500 mg/M491

Tris(2-(benzo[b]thiophen-2-yl)pyridineiridium, known as Ir(btpy)3, is an efficient red phosphorescent emitter (PHOLED). It is commonly used in organic light-emitting diodes and polymer solar cells as a dopant, and in barometric pressure probes due to its sensitivity to oxygen [2].

Wang et al. demonstrated that a higher Ir(btpy)3 doping concentration is beneficial to photon harvesting in the active layer, but the interpenetrating network of P3HT:PCBM can be damaged through high-temperature annealing treatment [3].

General Information

CAS number405289-74-9
Chemical formulaC39H24IrN3S3
Molecular weight823.08 g/mol
Absorptionλmax 292, 366, 408 nm in THF
Fluorescenceλem 596, 645 nm in THF
HOMO/LUMOHOMO 5.08 eV; LUMO 2.67 eV [1]
Synonyms
  • Tris(2-(benzo[b]thiophen-2-yl)pyridineiridium(III); 
  • Tris[2-(benzo[b]thiophen-2-yl)pyridinato-C3,N]iridium(III)
  • fac-Tris[2-(benzo[b]thiophen-2-yl)pyridinato-C3,N]iridium(III)
  • fac-Ir(btpy)3, Tris(2-(benzo[b]thiophen-2-yl)pyridineiridium(III) 
Classification / FamilyOrganometallic complex, phosphorescent red emitter, phosphorescence dopant OLEDs, polymer solar cells, sublimed materials

Product Details

Purity>99.0% (sublimed)
Melting point> 300 °C
ColourRed powder

*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.

Chemical Structure

ir(btpy)3 chemical structure
Chemical Structure of Tris(2-(benzo[b]thiophen-2-yl)pyridineiridium(III) [Ir(btpy)3]

Characterisation

1H NMR Ir(btpy)3

 1H NMR of fac-Tris[2-(benzo[b]thiophen-2-yl)pyridinato-C3,N]iridium(III) Ir(btpy)3 in CDCl3

HPLC ir(btpy)3

HPLC trace of Tris[2-(benzo[b]thiophen-2-yl)pyridinato-C3,N]iridium(III), Ir(btpy)3

Pricing

GradeOrder CodeQuantityPrice
Sublimed (>99.0% purity)M491100 mg£199.00
Sublimed (>99.0% purity)M491250 mg£399.00
Sublimed (>99.0% purity)M491500 mg£689.00

MSDS Documentation

Ir(btpy)3 MSDSIr(btpy)3 MSDS sheet

Literature and Reviews

  1. The Red Electroluminescence of Iridium Complex at Different Concentrations and Host Materials, W. Zhang et al., Appl. Mechanics and Mater., Ch. 2, 94-97 (2014); DIO: 10.4028/www.scientific.net/AMM.633-634.94.
  2. Structure–Property Relationship of Red- and Green-Emitting Iridium(III) Complexes with Respect to Their Temperature and Oxygen Sensitivity, N. Tian et al., Eur. J. Inorg. Chem. 2010, 4875–4885, DOI: 10.1002/ejic.201000610.
  3. Effect of Doping Phosphorescent Material and Annealing Treatment on the Performance of Polymer Solar Cells, Z. Wang et al., Inter. J. Photoenergy, 273586 (2013), http://dx.doi.org/10.1155/2013/273586.
  4. Red-green-blue polymer light-emitting diode pixels printed by optimized laser-induced forward transfer, J. Stewart et al., Appl. Phys. Lett. 100, 203303 (2012); http://dx.doi.org/10.1063/1.4717463.
  5. Homoleptic Cyclometalated Iridium Complexes with Highly Efficient Red Phosphorescence and Application to Organic Light-Emitting Diode, A. Tsuboyama et al., J. Am. Chem. Soc., 125, 12971-12979 (2003), DOI: 10.1021/ja034732d.
  6. Photopolymerization of N-Vinylcarbazole Using Visible-Light Harvesting Iridium Complexes as Photoinitiators, J. Lalevee et al., Macromolecules 45, 4134−4141 (2012), dx.doi.org/10.1021/ma3005229.

To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.

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