Tris(2-(benzo[b]thiophen-2-yl)pyridineiridium, known as Ir(btpy)3, is an efficient red phosphorescent emitter (PHOLED). It is commonly used in organic light-emitting diodes and polymer solar cells as a dopant, and in barometric pressure probes due to its sensitivity to oxygen [2].
Wang et al. demonstrated that a higher Ir(btpy)3 doping concentration is beneficial to photon harvesting in the active layer, but the interpenetrating network of P3HT:PCBM can be damaged through high-temperature annealing treatment [3].
CAS number | 405289-74-9 |
Chemical formula | C39H24IrN3S3 |
Molecular weight | 823.08 g/mol |
Absorption | λmax 292, 366, 408 nm in THF |
Fluorescence | λem 596, 645 nm in THF |
HOMO/LUMO | HOMO 5.08 eV; LUMO 2.67 eV [1] |
Synonyms |
|
Classification / Family | Organometallic complex, phosphorescent red emitter, phosphorescence dopant OLEDs, polymer solar cells, sublimed materials |
Purity | >99.0% (sublimed) |
Melting point | > 300 °C |
Colour | Red powder |
*Sublimation is a technique used to obtain ultra pure-grade chemicals. For more details about sublimation, please refer to the Sublimed Materials for OLED devices page.
Grade | Order Code | Quantity | Price |
Sublimed (>99.0% purity) | M491 | 100 mg | £199.00 |
Sublimed (>99.0% purity) | M491 | 250 mg | £399.00 |
Sublimed (>99.0% purity) | M491 | 500 mg | £689.00 |
Ir(btpy)3 MSDS sheet
To the best of our knowledge the technical information provided here is accurate. However, Ossila assume no liability for the accuracy of this information. The values provided here are typical at the time of manufacture and may vary over time and from batch to batch.
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